个旧花岗岩体北缘铟成矿带发现及其意义
The discovery and significance of the indium metallogenic belt in the northern margin of Gejiu granite
ES评分0
| DOI | 10.20086/j.cnki.yskw.2025.4056 |
| 刊名 |
Acta Petrologica et Mineralogica
|
| 年,卷(期) | 2025, 44(3) |
| 作者 |
|
| 作者单位 |
1. 昆明理工大学国土资源与工程学院, 云南 昆明 650093; |
| 摘要 |
稀散元素铟(In)属于关键金属,是新兴产业技术和国防安全领域的重要原料。我国是铟资源大国,滇东南地区是我国最重要的铟资源基地。本文对云南个旧花岗岩体北缘普雄铅锌成矿带中的挣财洞和老鹰窝等典型矿床开展了铟分布规律和赋存形式研究,闪锌矿LA-ICP-MS原位微量元素测试结果表明,挣财洞矿床闪锌矿中铟的含量在37.71×10-6~403.88×10-6之间,均值为157.44×10-6,老鹰窝铅锌矿床的闪锌矿中铟含量在378.58×10-6~1 060.08×10-6之间,均值为631.46×10-6,与国内典型富铟矿床闪锌矿中铟的含量属于一个数量级,明显高于国外典型富铟矿床。此外,普雄铅锌成矿带内还分布众多其他铅锌矿床(点),而闪锌矿又是铟的重要载体矿物,据此本文认为该铅锌成矿带也是重要的铟成矿带,有重要的研究和利用价值。
|
| Abstract |
Indium (In), a crucial metal, serves as a significant raw material in the domains of emerging industrial technologies as well as national defense and security. China is one of the most important countries of indium resources in the world, and southeast Yunnan plays the same role in our country. In this paper, the distribution and occurrence of indium in typical deposits such as Zhengcaidong and Laoyingwo in the Puxiong Pb-Zn metallogenic belt at the northern margin of Gejiu granite in Yunnan Province have been studied. LA-ICP-MS in situ trace element test of sphalerite shows that the indium content of sphalerite in Zhenngcaidong deposit ranges from 37.71×10-6 to 403.88×10-6, with an average of 157.44×10-6. The indium content of sphalerite in Laoyingwo Pb-Zn deposit ranges from 378.58×10-6 to 1 060.08×10-6, with an average of 631.46×10-6. The indium content in sphalerite is an order of magnitude higher than that in indium-rich deposits abroad. In addition, many Pb-Zn deposits (occurrences) occur in the Puxiong Pb-Zn metallogenic belt, and sphalerite is the dominate indium-bearing mineral in this region. Therefore, we suggest that the Puxiong Pb-Zn metallogenic belt is also an important indium metallogenic belt, which has important research and utilization values.
|
| 关键词 |
滇东南普雄地区;铅锌矿成矿带;个旧花岗岩体北缘;铟;超常富集
|
| KeyWord |
Puxiong district in southeast Yunnan Province; Pb-Zn ore metallogenic belt; north margin of Gejiu granite; indium; supernormal enrichment
|
| 基金项目 | |
| 页码 | 737-744 |
Cheng Yongsheng. 2012. A preliminary study on the law of rich-integrated ore of dispersed element indium
[J]. Acta Mineralogica Sinica, 32(S1): 18~19(in Chinese).
Cheng Yongsheng. 2013. Discussion on distribution characteristics and production law of indium-rich deposits
[J]. Acta Mineralogica Sinica, 33(S2): 199~200(in Chinese).
Cook N J, Ciobanu C L, Pring A, et al. 2009. Trace and minor elements in sphalerite: A LA-ICPMS study
[J]. Geochimica et Cosmochimica Acta, 73(16): 4 761~4 791.
Cook N J, Sundblad K, Valkama M, et al. 2011. Indium mineralisation in A-type granites in southeastern Finland: Insights into mineralogy and partitioning between coexisting minerals
[J]. Chemical Geology, 284(1~2): 62~73.
Guo Zhijuan, Song Yuntao, Xu Renting, et al. 2020. Indium distribution and enrichment characteristics in Gejiu Sn-polymetallic orefield area in Yunnan Province
[J]. Geoscience, 34(5): 908~916(in Chinese with English abstract).
Hou Zengqian, Chen Jun and Zhai Mingguo. 2020. Current status and frontiers of research on critical mineral resources
[J]. Chinese Science Bulletin, 65(33): 3 651~3 652(in Chinese with English abstract).
Hu Ruizhong, Wen Hanjie, Ye Lin, et al. 2020. Metallogeny of critical metals in the southwestern Yangtze Block
[J]. Chinese Science Bulletin, 65(33): 3 700~3 714(in Chinese with English abstract).
Ishihara S, Murakami H and Li X F. 2011a. Indium concentration in zinc ores in plutonic and volcanic environments: Examples at the Dulong and Dachang mines, South China
[J]. Bulletin of the Geological Survey of Japan, 62(7~8): 259~272.
Ishihara S, Murakami H and Marquez-Zavalia M F. 2011b. Inferred indium resources of the Bolivian tin-polymetallic deposits
[J]. Resource Geology, 61(2): 174~191.
Jiang Shaoyong and Wang Wei. 2022. How does the strategic key metal produce super-rich integrated ore?
[J]. Earth Science, 47(10): 3 869~3 871(in Chinese).
Jiang Shaoyong, Wen Hanjie, Xu Cheng, et al. 2019. Earth sphere cycling and enrichment mechanism of critical metals: Major scientific issues for future research
[J]. Bulletin of National Natural Science Foundation of China, 33(2): 112~118(in Chinese with English abstract).
Li Xiaofeng, Watanabe Yasushi and Mao Jingwen. 2007. Research situation and economic value of indium deposits
[J]. Mineral Deposits, 26(4): 475~480(in Chinese with English abstract).
Li Xiaofeng, Xu Jing, Zhu Yiting, et al. 2019. Critical minerals of indium: Major ore types and scientific issues
[J]. Acta Petrologica Sinica, 35(11): 3 292~3 302(in Chinese with English abstract).
Li Xiaofeng, Yang Feng, Chen Zhenyu, et al. 2009. Preliminary study on the genetic mechanism of indium in Dachang tin mine in Guangxi
[J]. Acta Mineralogica Sinica, 29(S1): 124~125(in Chinese).
Li Xiaofeng, Zhu Yiting and Xu Jing. 2020. Indium as a critical mineral: A research progress report
[J]. Chinese Science Bulletin, 65(33): 3 678~3 687(in Chinese with English abstract).
Li Y B, Tao Y, Zhu F L, et al. 2015. Distribution and existing state of indium in the Gejiu tin polymetallic deposit, Yunnan Province, SW China
[J]. Chinese Journal of Geochemistry, 34(4): 469~483.
Li Yuhua, Liu Fengxiang, Zhou Jiaxi, et al. 2019. Discovery and research significance of Puxiong niobium rare earth deposit in Jianshui, Yunnan Province
[J]. Acta Mineralogica Sinica, 39(4): 484(in Chinese).
Mao Jingwen, Cheng Yanbo, Guo Chunli, et al. 2008. Gejiu tin polymetallic ore-field: Deposit model and discussion for several points concerned
[J]. Acta Geologica Sinica, 82(11): 1 455~1 467(in Chinese with English abstract).
Mao Jingwen, Yuan Shunda, Xie Guiqing, et al. 2019. New advances on metallogenic studies and exploration on critical minerals of China in 21st century
[J]. Mineral Deposits, 38(5): 935~969(in Chinese with English abstract).
Pi Qiaohui, Hu Ruizhong, Wang Denghong, et al. 2015. Enrichment of indium in west ore belt of Dachang orefield: Evidence from ore textures and sphalerite geochemistry
[J]. Mineral Deposits, 34(2): 379~396(in Chinese with English abstract).
Rudnick R L and Gao S. 2014. Composition of the continental crust
[C]// Turekian H D, Holland K K. Treatise on Geochemistry. 2nd ed. Oxford: Elsevier, 1~51.
Schwarz-Schampera U and Herzig P M. 2002. Indium: Geology, Mineralogy, and Economics
[M]. Berlin, Heidelberg: Springer.
Tian Jing and Yang Guangshu. 2022. Trace element characteristics of sphalerite from Dulong tin-polymetallic deposit in southeast Yunnan and their geological significances
[J]. Geotectonica et Metallogenia, 46(6): 1 148~1 166(in Chinese with English abstract).
Wang Jiasheng, Ye Bin, Jiang Xiaojun, et al. 2024. New discovery of extraordinary enrichment of indium in Jiutoushan lead-zinc deposit in Jianshui, southeastern Yunnan and its significance
[J]. Bulletin of Mineralogy, Petrology and Geochemistry, 43(2): 463~466(in Chinese).
Wang Min, Zhou Jiaxi, Liu Fengxiang, et al. 2020. Mineralogy and elemental geochemistry of the Puxiong Nb-REE deposit in Jianshui City, southeast Yunnan Province, SW China
[J]. Acta Geologica Sinica, 94(12): 3 746~3 760(in Chinese with English abstract).
Wen Hanjie, Zhou Zhengbing, Zhu Chuanwei, et al. 2019. Critical scientific issues of super-enrichment of dispersed metals
[J]. Acta Petrologica Sinica, 35(11): 3 271~3 291(in Chinese with English abstract).
Werner T T, Mudd G M and Jowitt S M. 2017. The world's by-product and critical metal resources part Ⅲ: A global assessment of indium
[J]. Ore Geology Reviews, 86: 939~956.
Xu Jing and Li Xiaofeng. 2018. Spatial and temporal distributions, metallogenic backgrounds and processes of indium deposits
[J]. Acta Petrologica Sinica, 34(12): 3 611~3 626(in Chinese with English abstract).
Ye L, Cook N J, Ciobanu C L, et al. 2011. Trace and minor elements in sphalerite from base metal deposits in South China: A LA-ICPMS study
[J]. Ore Geology Reviews, 39(4): 188~217.
Ye Lin, Liu Yuping, Zhang Qian, et al. 2017. Trace and rare earth elements characteristics of sphalerite in Dulong super large Sn-Zn polymetallic ore deposit, Yunnan Province
[J]. Journal of Jilin University (Earth Science Edition), 47(3): 734~750(in Chinese with English abstract).
No. 209 Geological Party, Geological Bureau of Yunnan Nuclear Industry. 2018a. Verification Report of Resource Reserves of Pb-Zn Mine in Caidong, Puxiong Township, Jianshui County, Yunnan Province
[R](in Chinese).
No. 209 Geological Party, Geological Bureau of Yunnan Nuclear Industry. 2018b. Verification Report of Laoyingwo Pb-Zn Mine Resource Reserves in Jianshui County, Yunnan Province
[R] (in Chinese).
Zhai Mingguo, Wu Fuyuan, Hu Ruizhong, et al. 2019. Critical metal mineral resources: Current research status ang scientific issues
[J]. Bulletin of National Natural Science Foundation of China, 33(2): 106~111(in Chinese with English abstract).
Zhang Huishan, Li Yanguang, Quan Shoucun, et al. 2018. Geochemical characteristics of metallic sulfides from the Kaladaban deposit in Xinjiang and its implications for Pb-Zn ore-forming mechanism
[J]. Acta Petrologica Sinica, 34(8): 2 295~2 311(in Chinese with English abstract).
Zhang Qian, Liu Zhihao, Zhan Xinzhi, et al. 2004. Trace element geochemistry of Meng'entaolegai Ag-Pb-Zn-in deposit, Inner Mongolia, China
[J]. Acta Mineralogica Sinica, 24(1): 39~47(in Chinese with English abstract).
Zhang Qian and Wang Dapeng. 2019. Metallogenic regularity and prospecting direction of indium-rich deposits in China
[C]//Abstracts of the 9th National Metallogenic Theory and Prospecting Method Symposium(in Chinese with English abstract).
Zhang Ruijie. 2020. Metallogenic Metal Source of Jinding Giant Lead-Zinc Deposit, Yunnan Province: Constraints of Trace Elements of Sphalerite and Lead, Zinc and Strontium Isotopic Compositions
[D]. China University of Geosciences (Beijing), 28~37(in Chinese with English abstract).
Zhang Yinping, Shao Yongjun, Xiong Yiqu, et al. 2022. Metallogenic indication from geochemical characteristics of garnet in Gejiu Sn-Cu ore-concentrated area, Yunnan Province
[J]. Mineral Deposits, 41(4): 682~701(in Chinese with English abstract).
Zhao T P, Chen C, He X H, et al. 2022. A synthesis of the geology, spatial-temporal distribution and enrichment mechanism of granite-related indium deposits in China
[J]. Ore Geology Reviews, 146: 104932.
成永生. 2012. 关于分散元素铟的富集成矿规律初步探讨
[J]. 矿物学报, 32(S1): 18~19.
成永生. 2013. 关于富铟矿床分布特征及其产出规律的探讨
[J]. 矿物学报, 33(S2): 199~200.
郭志娟, 宋云涛, 徐仁廷, 等. 2020. 云南个旧锡多金属矿集区稀散元素铟的分布富集特征
[J]. 现代地质, 34(5): 908~916.
侯增谦, 陈 骏, 翟明国. 2020. 战略性关键矿产研究现状与科学前沿
[J]. 科学通报, 65(33): 3 651~3 652.
胡瑞忠, 温汉捷, 叶 霖, 等. 2020. 扬子地块西南部关键金属元素成矿作用
[J]. 科学通报, 65(33): 3 700~3 714.
蒋少涌, 王 微. 2022. 战略性关键金属是如何发生超常富集成矿的?
[J]. 地球科学, 47(10): 3 869~3 871.
蒋少涌, 温汉捷, 许 成, 等. 2019. 关键金属元素的多圈层循环与富集机理: 主要科学问题及未来研究方向
[J]. 中国科学基金, 33(2): 112~118.
李晓峰, Watanabe Yasushi, 毛景文. 2007. 铟矿床研究现状及其展望
[J]. 矿床地质, 26(4): 475~480.
李晓峰, 徐 净, 朱艺婷, 等. 2019. 关键矿产资源铟: 主要成矿类型及关键科学问题
[J]. 岩石学报, 35(11): 3 292~3 302.
李晓峰, 杨 锋, 陈振宇, 等. 2009. 广西大厂锡矿铟的成因机制初探
[J]. 矿物学报, 29(S1): 124~125.
李晓峰, 朱艺婷, 徐 净. 2020. 关键矿产资源铟研究进展
[J]. 科学通报, 65(33): 3 678~3 687.
李余华, 刘凤祥, 周家喜, 等. 2019. 云南建水普雄铌稀土矿床的发现与研究意义
[J]. 矿物学报, 39(4): 484.
毛景文, 程彦博, 郭春丽, 等. 2008. 云南个旧锡矿田: 矿床模型及若干问题讨论
[J]. 地质学报, 82(11): 1 455~1 467.
毛景文, 袁顺达, 谢桂青, 等. 2019. 21世纪以来中国关键金属矿产找矿勘查与研究新进展
[J]. 矿床地质, 38(5): 935~969.
皮桥辉, 胡瑞忠, 王登红, 等. 2015. 广西大厂锡多金属矿田西矿带稀散元素铟的富集规律研究——来自矿石组构和闪锌矿地球化学的证据
[J]. 矿床地质, 34(2): 379~396.
田 静, 杨光树. 2022. 滇东南都龙锡多金属矿床中闪锌矿微量元素组成特征及其地质意义
[J]. 大地构造与成矿学, 46(6): 1 148~1 166.
王加昇, 叶 彬, 江小均, 等. 2024. 滇东南建水九头山铅锌矿床铟超常富集新发现及其意义
[J]. 矿物岩石地球化学通报, 43(2): 463~466.
王 敏, 周家喜, 刘凤祥, 等. 2020. 滇东南建水普雄铌稀土矿床矿物学和元素地球化学特征
[J]. 地质学报, 94(12): 3 746~3 760.
温汉捷, 周正兵, 朱传威, 等. 2019. 稀散金属超常富集的主要科学问题
[J]. 岩石学报, 35(11): 3 271~3 291.
徐 净, 李晓峰. 2018. 铟矿床时空分布、成矿背景及其成矿过程
[J]. 岩石学报, 34(12): 3 611~3 626.
叶 霖, 刘玉平, 张 乾, 等. 2017. 云南都龙超大型锡锌多金属矿床中闪锌矿微量及稀土元素地球化学特征
[J]. 吉林大学学报(地球科学版), 47(3): 734~750.
云南省核工业二〇九地质大队, 2018a. 云南省建水县普雄乡挣财洞铅锌矿资源储量核实报告
[R].
云南省核工业二〇九地质大队, 2018b. 云南省建水县老鹰窝铅锌矿资源储量核实报告
[R].
翟明国, 吴福元, 胡瑞忠, 等. 2019. 战略性关键金属矿产资源: 现状与问题. 中国科学基金, 33(2): 106~111.
张辉善, 李艳广, 全守村, 等. 2018. 阿尔金喀腊达坂铅锌矿床金属硫化物元素地球化学特征及其对成矿作用的制约
[J]. 岩石学报, 34(8): 2 295~2 311.
张 乾, 刘志浩, 战新志, 等. 2004. 内蒙古孟恩陶勒盖银铅锌铟矿床的微量元素地球化学
[J]. 矿物学报, 24(1): 39~47.
张 乾, 王大鹏. 2019. 中国富铟矿床的成矿规律及找矿方向
[C]//第九届全国成矿理论与找矿方法学术讨论会论文摘要集.
张瑞杰. 2020. 云南金顶超大型铅锌矿床成矿金属来源——闪锌矿微量元素及铅、锌、锶同位素组成制约
[D]. 北京: 中国地质大学(北京), 28~37.
张银平, 邵拥军, 熊伊曲, 等. 2022. 云南个旧锡铜矿集区石榴子石地球化学特征及成矿指示
[J]. 矿床地质, 41(4): 682~701.